A solid-supported arylboronic acid catalyst for direct amidation
- Yihao Dua,
- Thomas Barbera,
- Sol Ee Lima,
- Henry S. Rzepab,
- Ian R. Baxendale*a,
- Andrew Whiting*a,
- a Centre for Sustainable Chemical Processes, Department of Chemistry, Durham University, Science Laboratories, South Road, Durham, UK
- a Department of Chemistry, Imperial College, South Kensington Campus, London, UKRead the publication that featured this abstract
An efficient heterogeneous amidation catalyst has been prepared by co-polymerisation of styrene, DVB with 4-styreneboronic acid, which shows wide substrate applicability and higher reactivity than the equivalent homogeneous phenylboronic acid, suggesting potential cooperative catalytic effects. The catalyst can be easily recovered and reused; suitable for use in packed bed flow reactors.
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