Automated glycan assembly of xyloglucan oligosaccharides

We report the automated glycan assembly of oligosaccharide fragments related to the hemicellulose xyloglucan (XG). Iterative addition of monosaccharide and disaccharide building blocks to a solid support provided seven cellulose and xyloglucan fragments including XXGG- and XXXG-type oligosaccharides.

• Pietro Dallabernardina^{a b}
• Frank Schuhmacher^{a b}
• Peter H. Seeberger^{a b}
• Fabian Pfrengle^{* a b}

• ^a Department of Biomolecular Systems, Max-Planck-Institute of Colloids and Interfaces, Am Mühlenberg 1, 14476 Potsdam, Germany
• ^b Freie Universität Berlin, Institute of Chemistry and Biochemistry, Arnimallee 22, 14195 Berlin, Germany

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