Automated glycan assembly of xyloglucan oligosaccharides

• Pietro Dallabernardina^{a b}
• Frank Schuhmacher^{a b}
• Peter H. Seeberger^{a b}
• Fabian Pfrengle^{* a b}

• ^a Department of Biomolecular Systems, Max-Planck-Institute of Colloids and Interfaces, Am Mühlenberg 1, 14476 Potsdam, Germany
• ^b Freie Universität Berlin, Institute of Chemistry and Biochemistry, Arnimallee 22, 14195 Berlin, Germany

We report the automated glycan assembly of oligosaccharide fragments related to the hemicellulose xyloglucan (XG). Iterative addition of monosaccharide and disaccharide building blocks to a solid support provided seven cellulose and xyloglucan fragments including XXGG- and XXXG-type oligosaccharides.

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