A monolith immobilised iridium Cp* catalyst for hydrogen transfer reactions under flow conditions

    • Maria Victoria Rojo* 1
    • Lucie Guetzoyan1
    • Ian. R. Baxendale1 2
    • 1 Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, UK
    • 2 Department of Chemistry, University of Durham, South Road, Durham, UK
    A monolith immobilised iridium Cp* catalyst for hydrogen transfer reactions under flow conditions

    An immobilised iridium hydrogen transfer catalyst has been developed for use in flow based processing by incorporation of a ligand into a porous polymeric monolithic flow reactor. The monolithic construct has been used for several redox reductions demonstrating excellent recyclability, good turnover numbers and high chemical stability giving negligible metal leaching over extended periods of use.

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